Investigation on La3+ and Dy3+ co-doped ceria ceramics with an optimized average atomic number of dopants for electrolytes in IT-SOFCs

In the present study, we investigate the fundamental properties of CeO₂ by selecting La³⁺ (57), and Dy³⁺ (66) as dopants with optimized average atomic number of 61.5, which lies in between Pm³⁺ (62) and Sm³⁺ (62) in accordance with the criteria for optimum doping. A system of co-doped ceria ceramics Ce_1–x–yLa_xDy_yO_2-δ ((x, y) = (0.00, 0.00), (0.025, 0.025), (0.05, 0.05), (0.075, 0.075), (0.10, 0.10), (0.00, 0.20) and (0.20, 0.00)) as electrolytes for intermediate temperature solid oxide fuel cells were successfully prepared by a well-known sol-gel auto-combustion route. In order to obtain dense samples, the prepared pellets were sintered in air at 1300 °C for 4 h using conventional furnace and relative densities of all the samples were found to be higher than 95%. Single phase cubic structure, microstructural density and elemental composition analysis of all the samples were studied by powder X-ray diffraction, scanning electron microscope and energy dispersive spectroscopy techniques, respectively. Raman spectroscopy analysis confirmed the formation of concentrated O^2-–vacancies in the co-doped ceria system. Impedance spectroscopy measurements revealed the high value of total ionic conductivity and low activation energy for the composition Ce_0.85La_0.075Dy_0.075O_2?δ i.e., 2.08 × 10^–2 S cm^–1 and 0.58 eV, respectively. Linear thermal expansion analyses of all the samples revealed the matched thermal expansion coefficients. Finally, these results recommend that the Ce_0.85La_0.075Dy_0.075O_2?δ sample can be useful as a solid electrolyte in IT-SOFC applications.     

极限工况下的管网“互联互通”改进方案

在全国天然气管道“主干互联、区域成网”(以下简称“互联互通”)基础格局逐渐形成的背景下,天然气管网规模日益扩大、管道分支和气源增加,并且分布不集中、输送方向可变,使得输气方案更加灵活,可以更好地解决某些地域的供气紧张问题;但受现有站场和设备的限制,暂不能满足某些多线组合极限工况,使得“互联互通”的初衷难以全部实现。为了使得现有的各输气干线在实现“互联互通”之后可以满足更多的多线组合工况,在分析“互联互通”背景下M管网工况变化的基础上,研发了可以进行水力仿真和压气站方案制订的计算软件,并对3种极限工况下的不同输气量情况进行了可行性试算,进而基于试算结果提出了相应的管网改进建议。研究结果表明:(1)经验证,软件计算误差满足要求;(2)在M管道某处增设压气站或在某些输气站场配置压缩机组;(3) M管网改进调整后,可以完成大部分的多线组合极限工况,真正实现“互联互通”的输气方案。结论认为,该研究成果有助于推进全国天然气管网早日实现“互联互通”。     

金属增材制造技术研究热点聚类分析

为深入分析金属增材制造技术分类和发展状况,采集中国期刊全文数据库(CNKI)收录的核心期刊上的768篇科技文献,借助文献分析可视化软件CiteSpace,对关键词聚类进行了全景式描绘,构建金属增材制造技术知识图谱,揭示该技术研究分类以及演化趋势。     

水氯镁石制备金属镁的过程集成与能量分析

以无水氯化镁和氧化镁作为中间产物，电解和热还原为两个关键方法，集成各种相关过程，构建了从水氯镁石到金属镁的综合过程网络，其中涉及24个物种、20个化学过程和25个工艺路线；建立了最低能耗分析模型用于简单和复合过程的能量分析；利用物质的标准生成焓和多温等压摩尔热容，计算得出全部反应过程及工艺过程的能量消耗和热量移除。结果表明基于还原法的最优路径是水氯镁石用石灰法转为氢氧化镁，进而煅烧成氧化镁，再铝热还原成金属镁，该过程能耗360.15 kJ/mol，放出热量–315.46 kJ/mol；基于电解法的最优路径是石灰乳法生成氢氧化镁，再煅烧成氧化镁，通过在熔融电解质中电解生成金属镁，该过程能耗738.54 kJ/mol，放出热量–135.42 kJ/mol。无水氯化镁制备耗能高，不在最优路径中。     

氢气非预混燃烧的流场输运特性分析

采用高精度直接数值模拟的方法对氢气非预混燃烧流场进行了精细的预测.模拟所求解的控制方程为三维可压缩的无量纲形式的Navier-Stokes方程,采用六阶精度紧致差分格式,结合基于详细化学反应和输运过程的FGM化学反应机制,利用768个处理器核、共近4.53亿网格点进行了基于CPU的大规模高效并行计算,分析氢气非预混燃烧特性,并进一步探讨了浮力对氢气燃烧流场输运特性的影响.研究发现,由于氢气燃烧过程中产生不同扩散性质的化学组分,使燃烧过程中遵循优势扩散的行为.这将影响流场的输运特性和火焰不稳定性的形成.在浮力驱动的氢气优势扩散燃烧流场中,对流是质量、动量及热量输运行为的主要影响因素,而无浮力火焰中优势扩散主导着流场的输运特性.平均统计结果表明,有浮力和无浮力的燃烧流场中都可以捕捉到逆梯度输运现象,且浮力会促进逆梯度输运行为的发生.     

井下作业面巷道切顶卸压施工设计探究

以井下作业面巷道切顶卸压施工设计为对象开展探究,结合具体工程实际,从切顶卸压爆破施工设计和爆破施工分析两个角度,对切顶卸压技术的全面应用进行总结分析,希望能够为其他矿井相似工程的开展提供借鉴与参考。     

3D MHD cross flow over an exponential stretching porous surface

The present study aims to investigate the effects of thermal‐diffusion and diffusion‐thermo onan magnetohydrodynamic convective flow of viscous fluids over an exponentially stretching sheet. Thermal radiation effects are also considered in the study. This analysis is carried out in three dimensions and a similarity transformation is adopted to get a set of ordinary differential equations from a set of partial differential equations. And the Fourth‐order Runge‐Kutta method and shooting technique along with the secant method are employed to find out an iterative solution. We also analyze here the influence of the variable magnetic field, nonuniform permeability and variable chemical reaction on the fluid flow. The impact of various pertinent parameters of interest has extensively been explored through graphs and tables. The major findings of the present study are that resistive Lorentz force diminishes the fluid velocity and uplifts the thermal as well as concentration fields. Inclusion of porous matrix improves the viscous drag force which in turn augments wall shear stresses and peters out the heat and mass transfer rates from the sheet. In addition, the thermal expansion coefficient has an inverse relation with temperature.     

闭式外腔循环太阳能墙集热效果实验研究

文章设计了闭式外腔循环太阳能墙系统,从理论和实验两方面研究太阳能墙传热传质规律。以大连市冬季为研究背景,基于对实验测温点不同时刻的持续监测,从逐时曲线中分析了不同环境下闭式外腔循环系统内部温度以及室内获得热量后室温的变化情况。结果表明,太阳能墙集热效率与太阳辐射强度密切相关,在晴朗天气下,白天部分时段单一太阳能墙就能满足采暖要求,不满足采暖要求时可以选择空气源热泵辅助采暖。     

Kevlar织物软壁包容环抗冲击数值仿真分析研究

针对机匣包容性问题,提出Kevlar平纹织物本构模型的拟合方法,分别采用单层壳、多层壳、层合壳三种有限元建模方式对Kevlar织物软壁包容环弹道冲击过程进行模拟,发展了机匣包容性仿真分析模型。结果表明,多层壳模型和层合壳模型的计算结果更准确,并且可以通过调节摩擦因子使仿真结果与试验结果更接近。在此基础上研究了撞击点位置和弹体入射姿态对弹体剩余速度的影响。结果表明:在较小偏移距离内,撞击点的位置对剩余速度的影响可以忽略不计;滚转角和俯仰角对剩余速度影响较小,而对于偏航角,当角度大于30°时,剩余速度会随着角度的增大明显呈下降趋势,且弹体出射姿态也会发生明显变化。